Dicaesium silver hexabromobismuthate

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Dicaesium silver hexabromobismuthate
Identifiers
3D model (JSmol)
  • InChI=1S/Ag.Bi.6BrH.2Cs/h;;6*1H;;/q+1;+3;;;;;;;2*+1/p-6
    Key: BGOXDRLKIQGIDG-UHFFFAOYSA-H
  • [Cs+].[Cs+].[Ag+].[Bi+3].[Br-].[Br-].[Br-].[Br-].[Br-].[Br-]
Properties
AgBiBr6Cs2
Molar mass 1062.084 g·mol−1
Appearance Orange crystals
Related compounds
Related compounds
 Caesium enneabromodibismuthate
Caesium hexabromobismuthate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Dicaesium silver hexabromobismuthate is an inorganic compound with the formula Cs2AgBiBr6. Being a stable double perovskite material, it is applied to photocatalytic reduction of carbon dioxide.[1]

Synthesis

Dicaesium silver hexabromobismuthate can be synthesized by mixing stoichiometrical caesium bromide, silver bromide and bismuth(III) bromide in 48% hydrobromic acid.[2] Its nanocrystals can be prepared using the hot-injection method in organic solvent at higher temperature.[1]

References

  1. ^ a b Zhou, L., Xu, Y. F., Chen, B. X., Kuang, D. B., & Su, C. Y. (2018). Synthesis and photocatalytic application of stable lead‐free Cs2AgBiBr6perovskite nanocrystals. Small, 14(11), 1703762.
  2. ^ Zhang, Z., Liang, Y., Huang, H., Liu, X., Li, Q., Chen, L., & Xu, D. (2019). Stable and highly efficient photocatalysis with lead‐free double‐perovskite of Cs2AgBiBr6. Angewandte Chemie International Edition, 58(22), 7263-7267.
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