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Organometallics
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Organometallic chemistry
Principles
Crystal field theory
Ligand field theory
18-electron rule
d electron count
Polyhedral skeletal electron pair theory
Isolobal principle
π backbonding
Dewar–Chatt–Duncanson model
Hapticity
spin states
Agostic interaction
Metal–ligand multiple bond
Reactions
Oxidative addition / reductive elimination
Migratory insertion
β-hydride elimination
Transmetalation
Carbometalation
Types of compounds
Gilman reagents
Grignard reagents
Cyclopentadienyl complexes
Transition metal indenyl complexes
Transition metal fullerene complexes
Metallocenes
Metal tetranorbornyls
Sandwich compounds
Half sandwich compounds
Transition metal acyl complexes
Transition metal carbene complexes
Transition metal carbyne complexes
Transition metal alkene complexes
Transition metal alkyne complexes
Transition-metal allyl complexes
Transition metal carbides
Applications
Carbonylation
Cativa process
Grignard reaction
Monsanto process
Olefin metathesis
Shell higher olefin process
Ziegler–Natta process
Related branches of
chemistry
Organic chemistry
Inorganic chemistry
Bioinorganic chemistry
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