Seleninyl fluoride
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| Names | |
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| Other names
selenium difluoride oxide
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| Identifiers | |
3D model (JSmol)
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| ChemSpider | |
PubChem CID
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| UNII | |
CompTox Dashboard (EPA)
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| Properties | |
| F2OSe | |
| Molar mass | 132.967 g·mol−1 |
| Appearance | colourless fuming liquid[1] |
| Boiling point | 125[1] °C (257 °F; 398 K) |
| Structure | |
| 3.18±0.02 D[2] | |
| Related compounds | |
Other anions
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selenium oxychloride selenium oxybromide |
Other cations
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thionyl fluoride |
Related compounds
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selenium dioxydifluoride |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Seleninyl fluoride is an oxyfluoride of selenium with the chemical formula SeOF2.
Preparation
Seleninyl fluoride can be produced by the reaction of selenium oxychloride and potassium fluoride.[3]
- 2 KF + SeOCl2 → 2 KCl + SeOF2
It can also be produced by the reaction of selenium tetrafluoride with water or selenium dioxide.[2]
- SeF4 + H2O → SeOF2 + 2 HF
- SeF4 + SeO2 → 2 SeOF2
The reaction of selenium dioxide and sulfur tetrafluoride also produces seleninyl fluoride.[4]
- SeO2 + SF4 → SeOF2 + SOF2
Reactions
Seleninyl fluoride reacts with xenon difluoride to form Xe(OSeF5)2.[4]
- 3 XeF2 + 2 SeOF2 → Xe(OSeF5)2 + 2 Xe
It reacts with fluorine gas and potassium fluoride to form pentafluoroselenium hypofluorite.[5][6]
- SeOF2 + KF → K+[SeOF3]− —F2→ K+[SeOF5]− —F2→ KF + SeOF6
Uses
Seleninyl fluoride have been used as specialty solvents.[7]
References
- ^ a b Holloway, John H.; Laycock, David (1983). "Preparations and Reactions of Inorganic Main-Group Oxide Fluorides". Advances in Inorganic Chemistry. Vol. 27. Elsevier. pp. 157–195. doi:10.1016/s0898-8838(08)60107-5. ISBN 9780120236275. ISSN 0898-8838.
- ^ a b Bowater, I.C.; Brown, R.D.; Burden, F.R. (1967). "The microwave spectrum, structure, and dipole moment of seleninyl fluoride". Journal of Molecular Spectroscopy. 23 (3). Elsevier BV: 272–279. Bibcode:1967JMoSp..23..272B. doi:10.1016/s0022-2852(67)80015-8. ISSN 0022-2852.
- ^ Paetzold, R.; Aurich, K. (1962). "Untersuchungen an Selen-Sauerstoff-Verbindungen. XIII. Bildung und Darstellung von SeOF2 und SeOCl2". Zeitschrift für anorganische und allgemeine Chemie (in German). 315 (1–2). Wiley: 72–78. doi:10.1002/zaac.19623150110. ISSN 0044-2313.
- ^ a b Seppelt, Konrad; Lentz, Dieter; Klöter, Gerhard; Schack, Carl J. (2007-01-05). "Selenium Tetrafluoride, Selenium Difluoride Oxide (Seleninyl Fluoride), and Xenon Bis[Pentafluorooxoselenate(VI)]". Inorganic Syntheses. Hoboken, NJ, USA: John Wiley & Sons, Inc. pp. 27–31. doi:10.1002/9780470132555.ch9. ISBN 9780470132555. ISSN 1934-4716.
- ^ James Everett Smith, George H. Cady (1970). "Reactions of fluoroxypentafluoroselenium". Inorganic Chemistry. 9 (6): 1442–1445. doi:10.1021/ic50088a029. ISSN 0020-1669. Retrieved 2022-02-02.
- ^ Seppelt, Konrad (1973). "Halogenderivate der Pentafluoroorthoselensäure". Chemische Berichte. 106 (1). Wiley: 157–164. doi:10.1002/cber.19731060119. ISSN 0009-2940.
- ^ House, James E. (2008). Inorganic chemistry. Academic Press. p. 524. ISBN 978-0-12-356786-4.