Prosolanapyrone-II oxidase

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Prosolanapyrone-II oxidase
Identifiers
EC no.1.1.3.42
Databases
IntEnzIntEnz view
BRENDABRENDA entry
ExPASyNiceZyme view
KEGGKEGG entry
MetaCycmetabolic pathway
PRIAMprofile
PDB structuresRCSB PDB PDBe PDBsum
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NCBIproteins

Prosolanapyrone-II oxidase (EC 1.1.3.42, Sol5, SPS, solanapyrone synthase (bifunctional enzyme: prosolanapyrone II oxidase/prosolanapyrone III cycloisomerase), prosolanapyrone II oxidase) is an enzyme with systematic name prosolanapyrone-II:oxygen 3'-oxidoreductase.[1][2][3] This enzyme catalyses the following chemical reaction

prosolanapyrone II + O2 prosolanapyrone III + H2O2

This enzyme participates in the biosynthesis of the phytotoxin solanapyrone by some fungi.

References

  1. ^ Kasahara K, Miyamoto T, Fujimoto T, Oguri H, Tokiwano T, Oikawa H, Ebizuka Y, Fujii I (June 2010). "Solanapyrone synthase, a possible Diels-Alderase and iterative type I polyketide synthase encoded in a biosynthetic gene cluster from Alternaria solani". ChemBioChem. 11 (9): 1245–52. doi:10.1002/cbic.201000173. PMID 20486243.
  2. ^ Katayama K, Kobayashi T, Oikawa H, Honma M, Ichihara A (May 1998). "Enzymatic activity and partial purification of solanapyrone synthase: first enzyme catalyzing Diels-Alder reaction". Biochimica et Biophysica Acta (BBA) - Protein Structure and Molecular Enzymology. 1384 (2): 387–95. doi:10.1016/s0167-4838(98)00040-5. PMID 9659400.
  3. ^ Katayama K, Kobayashi T, Chijimatsu M, Ichihara A, Oikawa H (February 2008). "Purification and N-terminal amino acid sequence of solanapyrone synthase, a natural Diels-Alderase from Alternaria solani". Bioscience, Biotechnology, and Biochemistry. 72 (2): 604–7. doi:10.1271/bbb.70600. PMID 18256508.

External links