Nitride iodide

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An iodide nitride is a mixed anion compound containing both iodide (I−) and nitride ions (N3−). Another name is metalloiodonitrides. They are a subclass of halide nitrides or pnictide halides.[1] Some different kinds include ionic alkali or alkaline earth salts, small clusters where metal atoms surround a nitrogen atom, layered group 4 element 2-dimensional structures (which could be exfoliated to a monolayer), and transition metal nitrido complexes counter-balanced with iodide ions. There is also a family with rare earth elements and nitrogen and sulfur in a cluster.

Related mixed-anion compounds include halogen variations: nitride fluoride, nitride chloride, and nitride bromide, and pnictogen variations phosphide iodide, arsenide iodide and antimonide iodides.

Production

Nitride iodides may be produced by heating metal nitrides with metal iodides. The ammonolysis process heats a metal iodide with ammonia.[2] A related method heats a metal or metal hydride with ammonium iodide. The nitrogen source could also be an azide or an amide.[2]

List

name formula formula
weight 		crystal
system 		space
group 		unit cell Å volume density comments ref
Li4NCl hexagonal R3 a=366.225 c=1977.18 Z=3 [3]
calcium nitride iodide Ca2NI P63/mmc a = 3.8095, c = 14.530, Z = 2 [4]
α-TiNI orthorhombic Pmmn a=3.941 b=3.51.5 c=8.955 Z=2 black [5]
NCr(I)(NiPr2)2 [6]
Cr(I)(N)(N(C(CD3)2CH3)(C6H3FMe))2 [7]
Zn2NI orthorhombic Pnma a=6.3590 b=6.2529 c=7.9549 <6 GPa [8]
strontium nitride iodide Sr2NI 316.15 trigonal R3m a = 4.0049 c = 23.055 Z=3 320.24 4.918 orange [9]
α-ZrNI orthorhombic Pmmn a=4.114 b=3.724 c=9.431 Z=2 orange [10][5]
β-ZrNI trigonal R3m a=3.718 c=31.381 Z=6 brown [5]
[(pcp)Mo(IV)(N)(I)][Na(15-crown-5)] pcp=C6H3(OPiPr2)2 [11]
Ba2NI
LiLa4N2I7 orthorhombic Pnma a = 13.7417, b = 12.1345, c = 10.7991 Z=4 @100K [12]
NaLa4N2I7 orthorhombic Pna21 a=14.0018 b=10.9315 c=12.1021 Z=4 5.361 colourless air sensitive [13]
Ce15N7I24 4245.6 orthorhombic Pnma a=12.060 b=32.216 c=16.360 Z=4 5.48 red; air sensitive [14]
NaCe4N2I7 orthorhombic Pna21 a=13.9703 b=10.8932 c=12.0194 Z=4 5.446 red air sensitive [13]
NaPr4N2I7 orthorhombic Pna21 a=13.9412 b=10.8578 c=11.9389 Z=4 5.524 yellowish green air sensitive [13]
NaNd4N2I7 orthorhombic Pna21 a=13.9135 b=10.86 c=11.86 Z=4 5.638 pinkish blue air sensitive [13]
(NdI2)3N [15]
(NdI2)3N(DME)4 [16]
NdI(S2N2)(THF) [17]
Nd3I5(S2N2)(S2)(THF)10 2088.72 monoclinic P21 a=12.393 b=43.389 c=12.684 β=90.013 Z=4 6820 2.034 yellow [15]
Ln3I5(S2)(S2N2)(THF)4(Phen)3 [18]
Ln3I5(S2)(S2N2)(THF)3(Py)7 [18]
(SmI)3N2(THF) [16]
ErI(S2N2)(THF) [17]
Nd2ErClI4-(S2)(S2N2)(THF)7 [17]
Nd2ErCl2I3(S2)(S2N2)(THF)7 [17]
(DyI2)3N [19]
Dy3I5(S2)(S2N2)(THF)10 [19]
Nd2DyI5(S2)(S2N2)(THF)7 [17]
Nd2DyI5(S3)(S2N2)(THF)9 2034.88 monoclinic P21/c a=23.1102 b=12.6551 c=23.8268 β =111.201 Z=4 6496.8 2.080 [20]
Nd2TbI5(S2)(S2N2)(THF)9 monoclinic P21/c a =23.1704 b =12.6340 c =23.8340, β =111.274° Z=4 [21]
Nd2TmI5(S2)(S2N2)(THF)9 monoclinic P21/c a =23.075 b =12.6540 c =23.809, β =111.460° Z=4 [21]
Nd2YbI5(S3)(S2N2)(THF)9 monoclinic P21/c a=23.0959 b=12.6632 c=23.8387 β =111.363 Z=4 6493.0 2.092 [20]
α-HfNI orthorhombic Pmmn a=4.10.67 b=3.6944 c=9.382 Z=2 [5][10]
β-HfNI trigonal R3m a=3.689 c=31.329 Z=6 brown [5]
ThNI tetragonal P4/nmm a=4.107 c=9.242 orange to golden grey [5][22]
UNI tetragonal P4/nmm a=3.99 c=9.20 Z=2 [5][23]

References

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  14. ^ Mattausch, Hansj Ürgen; Kremer, Reinhard K.; Simon, Arndt (April 1996). "Synthese, Kristallstruktur und magnetische Eigenschaften von Ce15N7I24". Zeitschrift für anorganische und allgemeine Chemie (in German). 622 (4): 649–654. doi:10.1002/zaac.19966220413. ISSN 0044-2313.
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