Lutetium acetylacetonate

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Lutetium acetylacetonate
Identifiers
3D model (JSmol)
  • InChI=1S/3C5H7O2.Lu/c3*1-4(6)3-5(2)7;/h3*3H,1-2H3;/q3*-1;+3
    Key: HXFHOORFYPCGNF-UHFFFAOYSA-N
  • CC(=O)[CH-]C(=O)C.CC(=O)[CH-]C(=O)C.CC(=O)[CH-]C(=O)C.[Lu+3]
Properties
C15H21LuO6
Molar mass 472.294 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Lutetium acetylacetonate is a coordination compound with the chemical formula Lu(C5H7O2)3, or Lu(acac)3 for short. The complex per se is unlikely to exist, but the dihydrate would be expected based on the behavior of other lanthanide tris(acetylacetonate)s. Consistent with this scenario, It forms adducts Lu(acac)3(phen) and Lu(acac)3(dipy) where phen and bipy are 1,10-phenanthroline and 2,2'-bipyridine, respectively.[1]

The complex is somewhat volatile.[2] It can be prepared by the reaction of trialkoxylutetium and acetylacetone.[3]

References

  1. ^ Andrey Yu. Rogachev, Andrey V. Mironov, Sergey I. Troyanov, Natalia P. Kuzmina, Alexander V. Nemukhin (May 2006). "Synthesis, crystal structures and theoretical study of mixed ligand complexes of lanthanides acetylacetonates with o-phenanthroline and 2,2′-dipyridyl: The unexpected inverted electrostatic trend in stability". Journal of Molecular Structure. 789 (1–3): 187–194. doi:10.1016/j.molstruc.2005.12.026. Archived from the original on 2020-02-25. Retrieved 2021-09-20.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  2. ^ Trembovetskii, G. V.; Martynenko, L. I.; Murav'eva, I. A.; Spitsyn, V. I. Synthesis and study of volatile rare earth acetylacetonates(in Russian). Doklady Akademii Nauk SSSR, 1984. 277 (6): 1411-1414. ISSN 0002-3264.
  3. ^ Gavrilenko, V. V.; Chekulaeva, L. A.; Savitskaya, I. A.; Garbuzova, I. A. Synthesis of yttrium, lanthanum, neodymium, praseodymium and lutetium alkoxides and acetylacetonates(in Russian). Izvestiya Akademi Nauk, Seriya Khimicheskaya, 1992. 11: 2490-2493. ISSN 1026-3500.
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