Gadolinium perrhenate

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Gadolinium perrhenate
Identifiers
3D model (JSmol)
  • anhydrous: InChI=1S/Gd.12O.3Re/q+3;;;;;;;;;;3*-1;;;
    Key: UQBMPTDTGOQFJN-UHFFFAOYSA-N
  • tetrahydrate: InChI=1S/Gd.4H2O.12O.3Re/h;4*1H2;;;;;;;;;;;;;;;/q+3;;;;;;;;;;;;;;3*-1;;;
    Key: KRJIIOBDMJEHQA-UHFFFAOYSA-N
  • anhydrous: [Gd+3].[O-][Re](=O)(=O)=O.[O-][Re](=O)(=O)=O.[O-][Re](=O)(=O)=O
  • tetrahydrate: [Gd+3].[O-][Re](=O)(=O)=O.[O-][Re](=O)(=O)=O.[O-][Re](=O)(=O)=O.O.O.O.O
Properties
Gd(ReO4)3
Solubility soluble in water and ethanol[1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Gadolinium perrhenate is an inorganic compound, with the chemical formula of Gd(ReO4)3. It can be obtained by dissolving an excess of gadolinium oxide in a perrhenic acid solution (240 g/L) in the presence of hydrogen peroxide, from which the hydrates are precipitated.[2] Its tetrahydrate loses water by heating to obtain the anhydrous form,[3] which then decomposes at high temperatures to generate gadolinium oxide and rhenium heptoxide.[2]

References

  1. ^ Plyushchev, V. E.; Varfolomeev, M. B. Anhydrous perrhenates of rare earth metals(in Russian). Zhurnal Prikladnoi Khimii (Sankt-Peterburg, Russian Federation), 1968. 41 (8): 1643-1646. ISSN: 0044-4618.
  2. ^ a b Varfolomeev, M. B.; Plyushchev, V. E. Europium and gadolinium perrhenates(in Russian). Zhurnal Neorganicheskoi Khimii, 1967. 12 (2): 353-358. ISSN: 0044-457X.
  3. ^ Varfolomeev, M. B.; Ivanova, E. D.; Lunk, Kh. I.; Hilmer, W.; Shamrai, N. B. Thermal stability of rare earth element perrhenate tetrahydrates (Ln(ReO4)3.4H2O)(in Russian). Zhurnal Neorganicheskoi Khimii, 1984. 29 (12): 2995-2998. ISSN: :0044-457X.
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