Atomicity (chemistry)
 | This article needs additional citations for verification. (July 2022) |
Atomicity is the total number of atoms present in a molecule of an element. For example, each molecule of oxygen (O2) is composed of two oxygen atoms. Therefore, the atomicity of oxygen is 2.[1]
In older contexts, atomicity is sometimes equivalent to valency. Some authors also use the term to refer to the maximum number of valencies observed for an element.[2]
Classifications
Based on atomicity, molecules can be classified as:
- Monoatomic (composed of one atom). Examples include He (helium), Ne (neon), Ar (argon), and Kr (krypton). All noble gases are monoatomic.
- Diatomic (composed of two atoms). Examples include H2 (hydrogen), N2 (nitrogen), O2 (oxygen), F2 (fluorine), and Cl2 (chlorine). Halogens are usually diatomic.
- Triatomic (composed of three atoms). Examples include O3 (ozone).
- Polyatomic (composed of three or more atoms). Examples include S8.
Atomicity may vary in different allotropes of the same element.
The exact atomicity of metals, as well as some other elements such as carbon, cannot be determined because they consist of a large and indefinite number of atoms bonded together. They are typically designated as having an atomicity of 1.
The atomicity of homonuclear molecule can be derived by dividing the molecular weight by the atomic weight. For example, the molecular weight of oxygen is 31.999,[3] while its atomic weight is 15.879;[4] therefore, its atomicity is approximately 2 (31.999/15.879 ≈ 2).
Examples
The most common values of atomicity for the first 30 elements in the periodic table are as follows:
| Atomic Number | Element | Atomicity |
|---|---|---|
| 1 | Hydrogen (H) | 2 |
| 2 | Helium (He) | 1 |
| 3 | Lithium (Li) | 1 |
| 4 | Beryllium (Be) | 1 |
| 5 | Boron (B) | 1 |
| 6 | Carbon (C) | 1 |
| 7 | Nitrogen (N) | 2 |
| 8 | Oxygen (O) | 2 |
| 9 | Fluorine (F) | 2 |
| 10 | Neon (Ne) | 1 |
| 11 | Sodium (Na) | 1 |
| 12 | Magnesium (Mg) | 1 |
| 13 | Aluminium (Al) | 1 |
| 14 | Silicon (Si) | 1 |
| 15 | Phosphorus (P) | 4 |
| 16 | Sulphur (S) | 8 |
| 17 | Chlorine (Cl) | 2 |
| 18 | Argon (Ar) | 1 |
| 19 | Potassium (K) | 1 |
| 20 | Calcium (Ca) | 1 |
| 21 | Scandium (Sc) | 1 |
| 22 | Titanium (Ti) | 1 |
| 23 | Vanadium (V) | 1 |
| 24 | Chromium (Cr) | 1 |
| 25 | Manganese (Mn) | 1 |
| 26 | Iron (Fe) | 1 |
| 27 | Cobalt (Co) | 1 |
| 28 | Nickel (Ni) | 1 |
| 29 | Copper (Cu) | 1 |
| 30 | Zinc (Zn) | 1 |
References
- ^ Deteclormination of Chlorine in Oxygen From Solid Chemical Oxygen Generators, SAE Internationally, doi:10.4271/arp1320
- ^ Spokoyny, Alexander M. (2013-04-30). "New ligand platforms featuring boron-rich clusters as organomimetic substituents". Pure and Applied Chemistry (in German). 85 (5): 903–919. doi:10.1351/PAC-CON-13-01-13. ISSN 1365-3075. PMC 3845684. PMID 24311823.
- ^ "Molecular oxygen | O2". ChemSpider.
- ^ "Edward W. Morley and the Atomic Weight of Oxygen - National Historic Chemical Landmark". American Chemical Society. Retrieved 2022-10-03.