Ammonium phosphomolybdate
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Names | |
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Other names
Ammonium molybdophosphate
Triammonium 12-molybdophosphate | |
Identifiers | |
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3D model (JSmol)
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ChemSpider | |
ECHA InfoCard | 100.031.545 |
EC Number |
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PubChem CID
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UNII | |
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Properties | |
(NH4)3PMo12O40 | |
Molar mass | 1876.35 g/mol |
Appearance | Yellow crystals |
Melting point | Decomposes |
Hazards | |
GHS labelling: | |
Warning | |
H315, H319, H335[2] | |
P261, P305+P351+P338[2] | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Ammonium phosphomolybdate is the inorganic salt of phosphomolybdic acid with the chemical formula (NH4)3PMo12O40. The salt contains the phosphomolybdate anion, a well known heteropolymetalate of the Keggin structural class.
Synthesis
Ammonium phosphomolybdate can be made by heating ammonium orthomolybdate combined with phosphoric acid and nitric acid, yielding ammonium nitrate, water, and a yellow precipitate of ammonium phosphomolybdate is obtained.[3]
- 12 (NH4)6Mo7O24(H2O)4 + 7 Na2HPO4(H2O) + 65 HNO3 → 7 (NH4)3Mo12PO40 + 51 NH4NO3 + 14 NaNO3 + 56 H2O
Normally, it often is as a hexahydrate, which is a dark yellow fine crystal, and poorly soluble in water.[3]
References
- ^ ChemicalBook: http://www.chemicalbook.com/ChemicalProductProperty_EN_CB6162083.htm
- ^ a b "Ammonium phosphomolybdate hydrate".
- ^ a b Dias, José Alves; Dias, Sílvia Cláudia Loureiro; Caliman, Ednéia (2014). "Keggin Structure Polyoxometalates". Inorganic Syntheses: Volume 36. Vol. 36. pp. 210–217. doi:10.1002/9781118744994.ch39. ISBN 9781118744994.
Categories:
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- Ammonium compounds
- Molybdates
- Inorganic phosphorus compounds
- Heteropoly acids