Bromine monoxide radical

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This article is about the compound BrO. For the oxoanion with the formula BrO−, see hypobromite. For the molecule Br2O, see Dibromine monoxide.
Bromine monoxide radical
Names
Other names
BrO radical, bromine monoxide, bromine(II) oxide
Identifiers
3D model (JSmol)
  • InChI=1S/BrO/c1-2
    Key: FMSOWMGJJIHFTQ-UHFFFAOYSA-N
  • Br[O]
Properties
BrO
Molar mass 95.903 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Bromine monoxide is a binary inorganic compound of bromine and oxygen with the chemical formula BrO.[1][2] A free radical, this compound is the simplest of many bromine oxides. The compound is capable of influencing atmospheric chemical processes.[3] Naturally, BrO can be found in volcanic plumes.[4][5] BrO is similar to the oxygen monofluoride, chlorine monoxide and iodine monoxide radicals.

Chemical properties

The compound is very effective as a catalyst of the ozone destruction. The chemical reaction of BrO and chlorine dioxide (OClO) results in ozone depletion in the stratosphere.[6]

References

  1. ^ Simpson, W. R.; Carlson, D.; Hoenninger, G.; Douglas, T. A.; Sturm, M.; Perovich, D.; Platt, U. (7 November 2006). "First-year sea-ice contact predicts bromine monoxide (BrO) levels better than potential frost flower contact". Atmospheric Chemistry and Physics. doi:10.5194/acpd-6-11051-2006. S2CID 11444056. Retrieved 11 May 2023.
  2. ^ "Bromine monoxide". NIST. Retrieved 11 May 2023.
  3. ^ Warnach, Simon; Sihler, Holger; Borger, Christian; Bobrowski, Nicole; Schmitt, Stefan; Schöne, Moritz; Beirle, Steffen; Platt, Ulrich; Wagner, Thomas (1 April 2021). "A global perspective on Bromine monoxide composition in volcanic plumes derived from three years of S5-P/TROPOMI data". Egu General Assembly Conference Abstracts. Harvard University: EGU21–1696. Bibcode:2021EGUGA..23.1696W. doi:10.5194/egusphere-egu21-1696. S2CID 241375642.
  4. ^ McGonigle, Andrew; Aiuppa, Alessandro; Bobrowski, Nicole; Tassi, Franco; Viveiros, Fátima (23 January 2020). Recent Advances in Volcanic Gas Science. Frontiers Media SA. p. 43. ISBN 978-2-88963-382-1. Retrieved 11 May 2023.
  5. ^ Schmidt, Anja; Fristad, Kirsten; Elkins-Tanton, Linda (8 January 2015). Volcanism and Global Environmental Change. Cambridge University Press. p. 116. ISBN 978-1-107-05837-8. Retrieved 11 May 2023.
  6. ^ "GES DISC". daac.gsfc.nasa.gov. Retrieved 11 May 2023.
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