Thallium(III) nitrate

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Thallium(III) nitrate
Names
IUPAC name
thallium(III) trinitrate
Other names
thallic nitrate
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.033.918 Edit this at Wikidata
UNII
UN number 2727
  • InChI=1S/3NO3.Tl/c3*2-1(3)4;/q3*-1;+3 ☒N
    Key: KLBIUKJOZFWCLW-UHFFFAOYSA-N ☒N
  • [Tl+3].O=[N+]([O-])[O-].[O-][N+]([O-])=O.[O-][N+]([O-])=O
Properties
Tl(NO3)3
Molar mass 390.398 g/mol
Appearance colorless solid
Melting point 103 °C (217 °F; 376 K)
Boiling point decomposes
decomposes
Hazards
GHS labelling:
GHS03: OxidizingGHS06: ToxicGHS08: Health hazard
Danger
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 4: Very short exposure could cause death or major residual injury. E.g. VX gasFlammability 1: Must be pre-heated before ignition can occur. Flash point over 93 °C (200 °F). E.g. canola oilInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazard OX: Oxidizer. E.g. potassium perchlorate
4
1
0
OX
NIOSH (US health exposure limits):
IDLH (Immediate danger)
 15 mg/m3
Safety data sheet (SDS) Fisher Scientific
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Thallium(III) nitrate, also known as thallic nitrate, is a thallium compound with chemical formula Tl(NO3)3.[1] It is normally found as the trihydrate. It is a colorless and highly toxic salt. It is a strong oxidizing agent useful in organic synthesis. Among its many transformations, it oxidizes methoxyl phenols to quinone acetals, alkenes to acetals, and cyclic alkenes to ring-contracted aldehydes.[2]

References

  1. ^ MSDS for thallium(III) nitrate[permanent dead link]
  2. ^ Mukund P. Sibi, Luiz F. Silva Jr., Vânia M. T. Carneiro "Thallium(III) Nitrate Trihydrate" Encyclopedia of Reagents for Organic Synthesis 2008 John Wiley & Sons. doi:10.1002/047084289X.rt085.pub2
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