Phosphate sulfate

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The phosphate sulfates are mixed anion compounds containing both phosphate and sulfate ions. Related compounds include the arsenate sulfates, phosphate selenates, and arsenate selenates.

Some hydrogen phosphate sulfates are superprotonic conductors.

List

chem mw crystal system space group unit cell volume density comment references
Sanjuanite Al2(PO4)(SO4)(OH)·9H2O [1]
Hotsonite Al11(SO4)3(PO4)2(OH)21 · 16H2O triclinic a=11.23, b=11.66 c=10.55 α=112° 32′, β=107° 32′ γ=64° 27′ refract: α = 1.519 γ = 1.521 [2]
Arangasite Al2F(PO4)(SO4)·9H2O monoclinic P2/a a = 7.073, b = 9.634, c = 10.827, β = 100.40°, Z = 2 725.7 [3]
peisleyite Na3Al16(SO4)2(PO4)10(OH)17 · 20H2O monoclinic a 13.31, b 12.62, c 23.15, β 110.0°, Z = 2 discredited [4]
peisleyite Na2Al9[(P,S)O4]8(OH)6·28H2O triclinic P1 a = 9.28, b = 11.98, c = 13.25, α = 91.3, β = 75.6, γ = 67.67°, Z = 4 1308 [5]
Woodhouseite CaAl3(PO4)(SO4)(OH)6 trigonal R3m a = 6.993, c = 16.386 693.95 3.0 Uniaxial (+) nω = 1.636 nε = 1.647 Birefringence: δ = 0.011 [6]
Ardéalite Ca2H(PO4)(SO4)•4H2O monoclinic a = 5.721, b = 30.95, c = 6.265, β= 117.26° Z = 4 986.11 2.32 [7]
Destinezite Diadochite Fe2(PO4)(SO4)(OH)•6H2O triclinic P1 a = 9.570, b = 9.716, c = 7.313, α = 98.74°, β = 107.90°, γ = 63.86° Z = 2 [8]
bohuslavite FeIII4(PO4)3(SO4)(OH)(H2O)10·nH2O (5 ≤ n ≤ 14) triclinic P1 a = 13.376 b = 13.338 c = 10.863 α = 92.80, β = 91.03, γ = 119.92°, Z = 2 1675.7 pink [9]
Borickyite (Ca,Mg)(Fe3+,Al)4(PO4,SO4,CO3)(OH)8·3–7.5H2O [10]
Camaronesite [Fe3+(H2O)2(PO3OH)]2(SO4)·1–2H2O trigonal R32 a = 9.0833, c = 42.944, Z = 9 3068.5 [11]
Fe3+4(PO4)3(SO4)(OH)·18H2O triclinic P1 a=13.376, b 13.338, c 10.863, α 92.80, β 91.03, γ 119.92° 1675.7 [12]
vanderheydenite Zn6(PO4)2(SO4)(OH)4·7H2O monoclinic P21/n a = 6.204 b = 19.619, c = 7.782, β = 90.67° 947.1 biaxial (–) α = 1.565, β = 1.580 γ = 1.582. 2V = 39.8° [13]
Svanbergite SrAl3(PO4)(SO4)(OH)6 trigonal R3m a = 6.97, c = 16.59 Z=3 697.98 3.2 Uniaxial (+) nω = 1.631 - 1.635 nε = 1.646 - 1.649 Birefringence: δ = 0.015 [14]
Birchite Cd2Cu2(PO4)2(SO4) ·5H2O a = 10.489 b = 20.901 c = 6.155 Z=4 1349.6 3.647 biaxial positive,

nα = 1.624, nβ = 1.636, nγ = 1.669, 2Vcalc = +63°.

[15]
Corkite PbFe3(OH)6SO4PO4 trigonal R3m a = 7.32, c = 17.02 Z=3 781.2 4.295 Uniaxial (-) nω = 1.930 nε = 1.930 n = 1.93 - 1.96 Birefringence 0.03 [16]
BaAl3(PO4)(SO4)(OH)6 trigonal R3m a = , c = Z=3 [17]
hinsdalite (Pb,Sr)Al3(PO4)(SO4)(OH)6 [18]
Tsumebite Pb2Cu(PO4,SO4)(OH) [19]
Delvauxite CaFe43+(PO4,SO4)2(OH)8·4–6H2O [20]
Rossiantonite Al3(PO4)(SO4)2(OH)2(H2O)10·4H2O triclinic P1 a = 10.3410, b = 10.9600, c = 11.1446, α = 86.985, β = 65.727, γ = 75.064°, Z = 2 1110.5 [21]
Schlossmacherite (H3O,Ca)Al3(AsO4,PO4,SO4)2(OH)6 [22]
Arthurite Cu(Fe3+)2(AsO4,PO4,SO4)2(O,OH)2·4(H2O) [23]
cobaltarthurite [23]
Phosphoinnelite Ba4Na3Ti3Si4O14(PO4,SO4)2(O,F)3 triclinic P1? a = 5.38, b = 7.10, c = 14.76; α = 99.00°, β = 94.94°, γ = 90.14° Z = 1 555 3.82 biaxial (+), α = 1.730, β = 1.745, and γ = 1.764, 2V 90° [24]
Francolite (Ca, Mg, Sr, Na)10(PO4, SO4, CO3)6F2–3 [25]
Al4(UO2)2(PO4)4(SO4)(OH)2 · 18H2O [26]
Al4(UO2)2(PO4)4(SO4)(OH)2 · 20H2O [26]
Coconinoite Fe2Al2(UO2)2(PO4)4(SO4)(OH)2 · 20H2O monoclinic C2/c a =12.45, b = 12.96, c = 17.22, β = 105.7° [26]
xiangjiangite Fe2Al2(UO2)2(PO4)4(SO4)(OH)2 · 22H2O tetragonal a = 7.17 Å, b = 7.17 Å, c = 22.22 Å Z=1 1,142 Biaxial (-) nα = 1.558 nβ = 1.576 nγ = 1.593 2V: 87° [27]

Artificial

chem mw crystal system space group unit cell Å volume density comment references
[H4N+]2·HSO4−·H2PO4− [28][29]
NH4(HSO4)0.45(H2PO4)0.55 orthorhombic [30]
18-crown[6]·[NH4][H2PO4]0.5[HSO4]0.5·H2O orthrhombic F2dd a=8.710 b= 28.868 c=31.206 Z=16 7846 1.346 dehydrate at 70° [31]
[(C2H5)4N+]2·HSO4−·H2PO4− Monoclinic C2/c a = 28.0787 b = 11.8671 c = 14.1533 β = 100.739° Z=8 4633.46 1.303 colourless; decompose at 353K [32]
(NH2CH2COOH)3(H2SO4)0.7(H3PO4)0.3 monoclinic called TGSP; colourless; ferroelectric, curie point 51 °C; pyroelectric
Na(HSO4)(H3PO4) monoclinic P 21 a = 5.449, b = 6.832, c = 8.718, β = 95.88°, Z = 2  322.8 [33]
K2(HSO4)(H2PO4) monoclinic P 21/c a = 11.150, b = 7.371, c = 9.436, β = 92.29°, Z = 4  774.9 [33]
K4(HSO4)3(H2PO4) triclinic P 1 a = 7.217, b = 7.521, c = 7.574, α = 71.52°, β = 88.28°, γ = 86.20°, Z = 1  389.1 [33]
K4(PO2F2)2(S2O7) 534.46 monoclinic C2/c a = 13.00, b = 7.543, c = 19.01, β = 130.07°, Z = 4 1426.5 2.489 colourless; pyrosulfate + difluorophosphate [34]
K3[O3SOPO2OSO3] [35]
H1−xTi2(PO4)3−x(SO4)x (x=0.5–1) [36]
Na2MgTi(SO4)(PO4)2 trigonal R3c a=8.4796 c=21.8091 Z=6 1358.1 2.818 [37]
K2MgTi(SO4)(PO4)2 cubic P213 a=9.8743 Z=4 962.84 2.872 [37]
Ca10-xNax(PO4)6-x(SO4)xF2 monoclinic [38]
NaFe2(PO4)(SO4)2 hexagonal R3c a=8.4243 c=21.973 [39]
NaFe1.4V0.6(PO4)(SO4)2 [40]
[Ni(C14H10N4)3]4(PO4)2(SO4) (C14H10N4=2,2'-bi-1H-benzimidazole) 3331.96 cubic I43d a = 24.964 Z=4 15558 1.423 green [41]
Rb2(HSO4)(H2PO4) monoclinic P21/n a=7.448, b=7.552, c=7.632, β=100.47°, Z=2 422.1 [42][43]
Rb2(HSO4)(H2PO4) monoclinic P21/c a=11.555, b=7.536, c=9.593, β=91.56, Z=4 853.0 at 160K [43]
Rb4(HSO4)3(H2PO4) orthorhombic P21212 a=7.612, b=14.795, c=7.446, Z=2 838.6 [42][43]
18-crown[6]·Rb[H2PO4]0.5[HSO4]0.5·3H2O monoclinic C2/c a=19.802 b=8.447 c=25.777 β=101.00° Z=8 4232 1.572 dehydrate at 70° [31]
Rb2MgTi(SO4)(PO4)2 [37]
Sr4(PO4)2SO4 [44]
NaZrMg(PO4)(SO4)2 hexagonal R3c [45]
NaZrCo(PO4)(SO4)2 hexagonal R3c [45]
NaZrNi(PO4)(SO4)2 hexagonal R3c [45]
NaZrCu(PO4)(SO4)2 hexagonal R3c [45]
NaZrZn(PO4)(SO4)2 hexagonal R3c [45]
NaZrAl(PO4)2(SO4) hexagonal R3c [45]
NaZrFe(PO4)2(SO4) hexagonal R3c [45]
H3OSb2(SO4)2(PO4) triclinic P1 a=5.134 b=7.908 c=12.855, α=81.401° β=87.253° γ=86.49° [46]
KSb2(SO4)2(PO4) triclinic P1 a=5.1453 =7.9149 c=12.6146, α=82.054° β=87.715° γ=86.655° [46]
RbSb2(SO4)2(PO4) triclinic P1 a=5.1531 b=7.957 c=12.845, α=81.801° β=87.676° γ=86.703° [46]
Cs2(HSO4)(H2PO4) cubic ao=4.926 >105 °C but can be supercooled [47]
Cs2(HSO4)(H2PO4) monoclinic P21/n a = 7.856 b = 7.732 c = 7.827, β= 99.92° Z=2 468.3 3.261 can substitute 2.3% ammonium; proton conductivity at 110 °C is 3×10−3 Ω−1cm−1 [48][49]
Cs3(HSO4)2(H2PO4) monoclinic C2/c a=19.824 b=7.859 c=19.047 β=100.20° Z=4 1387.2 3.302 stable against water solution 298-313K; phase transition at 411K [50]
Cs4(HSO4)3(H2PO4) monoclinic C2/c a=19.945 b=7.8565 c=8.9949 β=100.119° Z=3 1387.5 3.301 colourless [51][52]
Cs5(HSO4)2(H2PO4)3 cubic I43d a=14.5668 over 381K goes to tetragonal a=4.965 c=5.016 [53]
Cs6H(HSO4)3(H2PO4)4 cubic I43d a=14.4758 3033.38 3.236 colourless [54]
Cs5(HSO4)3(H2PO4)2 monoclinic C2/c a=34.07 Å,b=7.661,c=9.158,β=90.44° 2390 3.198 [55]
18-crown[6]·Cs[H2PO4]0.5[HSO4]0.5·3H2O monoclinic C2/c a=19.840 b=8.460 c=26.19 β=101.14 Z=8 4313 1.689 dehydrate at 70° [31]
CsNH4(HSO4)(H2PO4) [56]
Cs3NH4(HSO4)3(H2PO4) [56]
Cs2MgTi(SO4)(PO4)2 [37]
Ba4(PO4)2SO4 [44]
NaBa6Zr(PO4)5SO4 cubic I43d a = 10.5449 Z=4 1172.54 eulytite mineral structure [44]
Ba2Sr2(PO4)2SO4 [44]
Ba3Sr(PO4)2SO4 [44]
Ce2O(HPO4)2(SO4). 4H2O CeIV [57]
Ce2O(HPO4)2.4(SO4)0.6. 2H2O CeIII [58]
[enH2]0.5[CeIII(PO4)(HSO4)(OH2)] monoclinic P21/a a=12.999 b=7.150 c=9.212 β=95.33 cream colour [59]
KSr2Eu(PO4)2SO4 [44]
RbSr2Eu(PO4)2SO4 [44]
CsSr2Eu(PO4)2SO4 [44]
[enH2]0.5[Ho(HPO4)(SO4)(H2O)] monoclinic P21/a a = 12.938 b = 6.834 c = 9.100 β = 88.12° [60]
Pb2Mg2(PO4)2SO4 [44]
MgPb3(PO4)2(SO4) cubic I43d a = 10.299 Z=4 1092.4 5.67 [61]
CaPb3(PO4)2(SO4) cubic I43d a = 10.296 Z=4 1091.5 5.77 [61]
MnPb3(PO4)2(SO4) cubic I43d a = 10.258 Z=4 1079.4 5.92 [61]
CoPb3(PO4)2(SO4) cubic I43d a = 10.356 Z=4 1110.6 5.78 [61]
NiPb3(PO4)2(SO4) cubic I43d a = 10.434 Z=4 1135.9 5.65 [61]
CuPb3(PO4)2(SO4) cubic I43d a = 10.422 Z=4 1132.0 5.70 [61]
ZnPb3(PO4)2(SO4) cubic I43d a = 10.449 Z=4 1140.8 5.67 [61]
CdPb3(PO4)2(SO4) cubic I43d a = 10.315 Z=4 1097.5 6.17 [61]
SrPb3(PO4)2(SO4) cubic I43d a = 10.369 Z=4 1114.8 5.93 [61]
Th2(PO4)2SO4·2 H2O decompose 450 °C [62]

Organic derivatives

A catenated sulfophosphate has the sulfur and phosphorus joined by an oxygen atom. In biochemistry, metabolism of sulfate may use such a group, for example with adenosine-5'-phosphosulfate.[63]

References

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